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These cations react with dissolved oxygen and are deposited back on the metal as oxides, forming a passive oxide film under the influence of an electric field. In principle, electrical energy can be converted into chemical energy as in the case of electrolysis of copper ion reduction where the cell potential is In addition, can be predicted by the Nernst equation, eq. (2.32). Thus, anism of scale growth is related to metal cations diffusing through the oxide scale to react with oxygen at the oxide-gas interface.
Pages: 764
Publisher: Wiley-Interscience; 6 edition (April 12, 2000)
ISBN: 0471394637
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