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Why? is placed in hydrochloric acid (HCl), and 3.15 Calculate the equilibrium constant at 25°C for the electrochemical cell shown in Figure 2.4. [ Solution: 3.16 Show that be defined by the Nernst equation. where the local potential E can 3.17 If an electrochemical cell operates at 10 amps, 25°C, and 101 kPa for 30 minutes, calculate a) the number of moles and b) the weight of copper would be produced. [Solution: a) N = 0.093 moles and b) W = 5.93 grams]. 3.18 a) Derive the Arrhenius equation from the general definition of the activation energy of any rate reaction process and determine the Arrhenius constants if and b) Plot vs. 3.19 Plot the given conductivity data vs. the aqueous concentration at 25°C and 1 atm. (The data was taken from Ref. [5]).
Pages: 285
Publisher: Springer; 2013 edition (June 14, 2013)
ISBN: 3642360246
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According to the model in Figure 3.3, the metal oxidation process can be represented by the following redox stoichiometric reaction On the other hand, if this reaction is reversed, then the metal cations in solution, specifically at the electrode/electrolyte interface, are deposited (plated) on the metal electrode , cited: Electrochemistry Using Nanometer-Sized Electrodes
http://zolo.vip/library/electrochemistry-using-nanometer-sized-electrodes. The metal in the corrosive solution essentially acts as a short-circuited galvanic cell. Different areas of the surface act as anode and cathode, at the anodic areas the metal is oxidized to an oxide while at the cathodic areas the dissolved oxygen is being reduced. The spontaneous complementary oxidation/reduction processes of "rusting" are spatially separated while an electrical current is flowing "internally" from one part of the corroding metal to another; the current is totally "wasted" as it produces no useful work but only generates heat. (A cell arrangement like this is often called a "local cell.") Corrosion products are typically oxides, but other products (e.g., sulfides) can also form depending on the environment ref.: Chemical Thermodynamics, download epub
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