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Choose graphs of first integral or differential to see principles applied. The (cathodic) current density, j(η) at the overpotential η is: j(η) = dεf (ε)ρ(ε)i(ε; η); i(ε; η) = eΓox W(ε; η) (1) W(ε; η) is the rate constant and i(ε; η) the current density from a given electronic level ε, f(ε) the Fermi function, ρ(ε) the electronic level density, Γ ox the population of the oxidized state of the redox molecules, and e is the electronic charge.
Pages: 368
Publisher: Springer; 1 edition (June 30, 1987)
ISBN: 0306425041
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